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Mechanically fabricated Metal–organic framework/resin composite nanoparticles for efficient basic catalysis
Author(s) -
Zhang ZhiHui,
Qian BingBing,
Sheng PanPan,
Yang Sen,
Huang XianFeng,
Wang JinLong,
Chen Qun,
Wang Liang,
He MingYang
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4788
Subject(s) - chemistry , catalysis , knoevenagel condensation , composite number , reusability , imidazolate , metal organic framework , zeolitic imidazolate framework , reaction conditions , condensation reaction , chemical engineering , organic chemistry , composite material , adsorption , materials science , software , computer science , engineering , programming language
Zeolitic imidazolate framework‐8 (ZIF‐8) was successfully composited with an anionic basic resin 201 × 7 (717‐resin) to provide a novel ZIF‐8/717‐resin composite. Its catalytic activity toward the Knoevenagel condensation reaction was evaluated. Results showed that ZIF‐8/717‐resin composite could efficiently catalyze this reaction, affording the corresponding products in good to excellent yields. Good functional group tolerance, mild reaction conditions, good stability and reusability of the catalyst are the major features of present protocol.