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Coordination‐driven self‐assembly of Cp * Rh‐based rectangles in novel families of hetero‐bimetallic metal–organic frameworks
Author(s) -
Lin Lin,
Lin Yuejian,
Jin Guoxin
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4759
Subject(s) - chemistry , bimetallic strip , ethylenediamine , crystallography , metal , crystal structure , single crystal , metal ions in aqueous solution , triazole , ion , 1,2,4 triazole , stereochemistry , inorganic chemistry , organic chemistry
The crystal and molecular structures of a series of structurally related 1,2,3‐triazole‐4,5‐dicarboxylate (LHtzdc = 1,2,3‐triazole‐4,5‐dicarboxylate) ligands for second metal ions were established via single‐crystal X‐ray structural analysis. [Cu (en)] 2+ (en = ethylenediamine) was selected as a second metal ion, the two spare sites of the O atom from LHtzdc are coordinated to a single [Cu (en)] 2+ , and the [Cu (en)] 2+ metal centres act as two outer pockets, which is an effective and innovative method of controlling the assembly of heterometallic cages.