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Sonochemical synthesis of a two‐dimensional supramolecular polymer with nanoporous morphology, linear thallophilic and covalent hydrogen‐bonding interactions
Author(s) -
Yusefi Sahar,
Akhbari Kamran,
White Jonathan,
Phuruangrat Anukorn
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4747
Subject(s) - chemistry , thermogravimetric analysis , supramolecular chemistry , hydrogen bond , covalent bond , nanoporous , crystallography , scanning electron microscope , polymer , supramolecular polymers , infrared spectroscopy , crystal structure , polymer chemistry , molecule , organic chemistry , materials science , composite material
A new thallium‐based supramolecular polymer [Tl( μ 3 –3‐HClb)( μ 3 –3‐Clb)] n ( 1 ), (3‐HClb = 3‐chloroperbenzoic acid), has been synthesized and structurally characterized by single crystal X‐ray crystallography. It has a two‐dimensional structure with linear thallophilic and covalent hydrogen‐bonding interactions. In order to evaluate the effects of concentration, ultrasonic irradiation and type of solvents on structure, morphology and thermal behavior of 1 , some experiments were designed, and eight samples of 1 were synthesized under different conditions. These samples were characterized by IR spectroscopy, thermogravimetric and differential thermal analyses, X‐ray powder diffraction and scanning electron microscopy.