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Fe 3 O 4 @SiO 2 ‐copper sucrose xanthate as a green nanocatalyst for N‐, O‐ and S‐arylation
Author(s) -
Radfar Iman,
Kazemi Miraki Maryam,
Esfandiary Naghmeh,
Ghandi Leila,
Heydari Akbar
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4619
Subject(s) - xanthate , chemistry , heteroatom , moiety , copper , catalysis , nanoparticle , carbon disulfide , sucrose , nuclear chemistry , organic chemistry , polymer chemistry , medicinal chemistry , inorganic chemistry , nanotechnology , ring (chemistry) , materials science
Formation of C(sp 2 )–X bonds was carried out using a Fe 3 O 4 @SiO 2 ‐copper(I) sucrose xanthate nanoparticle catalyst with the aid of the copper(I) xanthate moiety in the catalyst which was prepared from the reaction between sucrose and carbon disulfide through an alkaline medium via the traditional Zeise approach. Various techniques were employed for the characterization of these novel nanoparticles. Three sorts of heteroatoms, N, O and S, successfully underwent heteroatom arylation to produce secondary or tertiary amines, ethers and thioethers, respectively.