A unique combination of KI/ZnFe 2 O 4  as a catalyst for oxidative Strecker reaction | Zendy

Ghandi Leila | Zendy; Kazemi Miraki Maryam | Zendy; Karimi Meghdad | Zendy; Radfar Iman | Zendy; Heydari Akbar | Zendy

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A unique combination of KI/ZnFe 2 O 4 as a catalyst for oxidative Strecker reaction

Author(s) -

Ghandi Leila,

Kazemi Miraki Maryam,

Karimi Meghdad,

Radfar Iman,

Heydari Akbar

Publication year - 2019

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.4616

Subject(s) - chemistry , strecker amino acid synthesis , catalysis , aqueous solution , oxidative phosphorylation , organic chemistry , reaction conditions , combinatorial chemistry , biochemistry , enantioselective synthesis

α‐Aminonitriles as key intermediates for the preparation of α‐amino acid derivatives, amides, diamines, peptides, proteins and heterocycles were synthesized through methylarene oxidation in the Strecker reaction using a unique combination of KI/ZnFe 2 O 4 as the best catalyst and aqueous tert ‐butyl hydroperoxide as oxidant. A wide range of amines and methylarenes were converted to the corresponding products. Operational simplicity, short reaction time and recyclability of the catalyst are advantages of this protocol.

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