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Activated carbon‐supported cobalt molybdate as a heterogeneous catalyst to activate peroxymonosulfate for removal of organic dyes
Author(s) -
Tao Xiaoming,
Wu Yunhai,
Wu Yunying,
Zhang Bing,
Sha Haitao,
Cha Ligen,
Liu Ningning
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4572
Subject(s) - catalysis , chemistry , molybdate , cobalt , calcination , nuclear chemistry , heterogeneous catalysis , inorganic chemistry , organic chemistry
Activated carbon‐supported cobalt molybdate (CoMoO 4 /AC) composite was conveniently fabricated using a simple hydrothermal route and high‐temperature calcination, aiming to create a novel heterogeneous catalyst for activation of peroxymonosulfate (PMS) to degrade organic dyes. The CoMoO 4 /AC catalyst was characterized using scanning electron microscopy, powder X‐ray diffraction, energy‐dispersive spectroscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, elemental mapping analysis and X‐ray photoelectron spectroscopy. Efficient catalytic activity, high stability and superior reusability were observed. Additionally, the catalytic performance of CoMoO 4 /AC was systematically assessed through numerous controlled experiments and several operational factors, such as catalyst dosage, oxidant dosage, reaction temperature, initial pH and catalyst stability. Under the condition of CoMoO 4 /AC = 0.1 g l −1 , oxidant = 2.0 mM, dye = 100 mg l −1 , T = 25°C, the removal of methylene blue reached 90% within 60 min without pH adjustment. Batch experiment results showed that the degradation of organic dye relied upon the dosage of catalyst and oxidant and reaction temperature. Further, high catalyst and oxidant dosage, as well as high reaction temperature, were favorable for dye removal. Moreover, quenching experiments suggested that the CoMoO 4 /AC catalyst successfully activated PMS to generate sulfate and hydroxyl radicals. A rational mechanism is proposed based on a non‐radical process and a free radical process. The result revealed that the enhanced active sites were mainly ascribed to the synergistic effects between Co species and oxygen‐containing functional groups (especially ketone groups) on the catalyst surface. The findings of this study demonstrated the as‐prepared CoMoO 4 /AC composite has potential superiority for refractory organic contaminant removal from water.