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Synthesis of tetracyanoethylene‐substituted ferrocene and its device properties
Author(s) -
Kivrak Arif,
Zobi Cengiz,
Torlak Yasemin,
Çamlısoy Yeşim,
Kuş Mahmut,
Kivrak Hilal
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4512
Subject(s) - ferrocene , chemistry , organic solar cell , energy conversion efficiency , tetracyanoethylene , photovoltaic system , electrochemistry , small molecule , band gap , molecule , thermal stability , nanotechnology , chemical engineering , optoelectronics , photochemistry , electrode , organic chemistry , materials science , polymer , ecology , biochemistry , engineering , biology
Small organic molecules are promising candidates for cheaper, flexible and good‐performance sources for organic solar cells (OSCs) due to their easy fabrication, low cost and slightly cheaper processing. However, the lower power conversion efficiency of OSCs is the main problem for their applications. Ferrocene structures could be the best candidates for the active layers of OSCs due to their unique properties such as thermal and chemical stability. The electrochemical, electro‐optical and solar cell performances of 2,5‐dicyano‐3‐ferrocenyl‐4‐ferrocenylethynylhexa‐2,4‐dienedinitrile (DiCN‐Fc) structures were investigated. First, the electrochemical and electro‐optical properties were examined for finding the highest occupied and lowest unoccupied molecular orbital values and bandgap of DiCN‐Fc. The best photovoltaic performance was obtained with 7 wt% of DiCN‐Fc loading, with a power conversion efficiency of about 4.27%. In the light of our investigations, ferrocenyl‐substituted small organic molecules could contribute to the development of organic photovoltaic devices.