Synthesis and behavior in solution of the triple cubane‐ and windmill‐type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh) 4 W 4 O 16 ] | Zendy

Nishikawa Koji | Zendy; Kido Koichi | Zendy; Yoshida Jun'ichi | Zendy; Nishioka Takanori | Zendy; Kinoshita Isamu | Zendy; Breedlove Brian K. | Zendy; Hayashi Yoshihito | Zendy; Uehara Akira | Zendy; Isobe Kiyoshi | Zendy

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Synthesis and behavior in solution of the triple cubane‐ and windmill‐type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh) 4 W 4 O 16 ]

Author(s) -

Nishikawa Koji,

Kido Koichi,

Yoshida Jun'ichi,

Nishioka Takanori,

Kinoshita Isamu,

Breedlove Brian K.,

Hayashi Yoshihito,

Uehara Akira,

Isobe Kiyoshi

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.447

Subject(s) - cubane , chemistry , windmill , cluster (spacecraft) , tungsten , crystallography , type (biology) , oxide , stereochemistry , diffraction , crystal structure , organic chemistry , physics , ecology , programming language , optics , wind power , computer science , electrical engineering , biology , engineering

Two geometrical isomers of a [(Cp*Rh) 4 W 4 O 16 ] oxide cluster, a triple cubane‐type and a windmill‐type, are isolated selectively from the systems of [Cp*Rh] 2+ and [WO 4 ] 2− in CH 3 CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X‐ray diffraction. Copyright © 2003 John Wiley & Sons, Ltd.

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