Premium
Synthesis and behavior in solution of the triple cubane‐ and windmill‐type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh) 4 W 4 O 16 ]
Author(s) -
Nishikawa Koji,
Kido Koichi,
Yoshida Jun'ichi,
Nishioka Takanori,
Kinoshita Isamu,
Breedlove Brian K.,
Hayashi Yoshihito,
Uehara Akira,
Isobe Kiyoshi
Publication year - 2003
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.447
Subject(s) - cubane , chemistry , windmill , cluster (spacecraft) , tungsten , crystallography , type (biology) , oxide , stereochemistry , diffraction , crystal structure , organic chemistry , physics , ecology , programming language , optics , wind power , computer science , electrical engineering , biology , engineering
Two geometrical isomers of a [(Cp*Rh) 4 W 4 O 16 ] oxide cluster, a triple cubane‐type and a windmill‐type, are isolated selectively from the systems of [Cp*Rh] 2+ and [WO 4 ] 2− in CH 3 CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X‐ray diffraction. Copyright © 2003 John Wiley & Sons, Ltd.