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Synthesis and characterization of MCM‐41‐Biurea‐Pd as a heterogeneous nanocatalyst and using its catalytic efficacy in C–C, C–N and C–O coupling reactions
Author(s) -
Batmani Hana,
Noroozi Pesyan Nader,
Havasi Forugh
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4419
Subject(s) - chemistry , aryl , catalysis , heteroatom , stille reaction , mcm 41 , heterogeneous catalysis , halide , solvent , coupling reaction , phenols , organic chemistry , combinatorial chemistry , mesoporous material , ring (chemistry) , alkyl
MCM‐41‐Biurea‐Pd is introduced as a new, heterogeneous and reusable catalyst for C–C and C–heteroatom bond formation between various aryl halides, phenols and amines, in the presence of Ph 3 SnCl (Stille reaction) in PEG‐400 as a green solvent at room temperature. The structure of the functionalized MCM‐41 was analysed using various techniques.