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Synthesis and characterization of Ni (II) complexes supported by phenoxy/naphthoxy‐imine ligands with pendant N ‐ and O ‐donor groups and their use in ethylene oligomerization
Author(s) -
Oliveira L.L.,
Silva S.M.,
Casagrande A.C.A.,
Stieler R.,
Casagrande O.L.
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4414
Subject(s) - chemistry , imine , ethylene , nickel , selectivity , catalysis , monomer , ligand (biochemistry) , medicinal chemistry , polymer chemistry , hexene , quinoline , 1 butene , stereochemistry , organic chemistry , polymer , biochemistry , receptor
A series of new Ni(II) complexes of general formula Ni{ZNO} Br ( 2a‐i ) (ZNO = phenoxy/naphthoxy‐imine with pendant N‐ and O‐donor groups) were prepared and characterized by elemental analysis, IR spectroscopy, ESI‐HRMS, and by X‐ray crystallography for 2e . In the solid state, 2e features a monomeric structure with κ 3 coordination of the monoanionic naphthoxy‐imine‐quinoline ligand onto the nickel center. Upon activation with MAO, both classes of nickel catalysts were able to produce selectively 1‐butene (81.5–92.1 wt%) with turnover frequencies (TOFs) varying from 3,100 to 24,300 mol(C 2 H 4 ) mol (Ni) −1  h −1 . Nickel precatalysts bearing phenoxy‐imine ligands were much more active than its naphthoxy analogous under the same conditions. The use of a mixture of cocatalysts (MAO/TMA or MAO/TiBA) resulted in poor activities; however the presence of TiBA in the milieu led to a significant improvement on selectivity for 1‐hexene (25.5 wt%). Under optimized conditions ([Ni] = 10 μmol, 30 °C, oligomerization time = 5 min, 20 bar ethylene, [Al]/[Ni] = 600), precatalyst 2c led to TOF = 59,900 mol(C 2 H 4 ) mol(Ni) −1 h − 1 and selectivity for 1‐butene of 89.5 wt%.

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