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Crystallographic report: Bis(isonicotinonitrile)cadmium diselencyanate, [Cd(SeCN) 2 (pyCN) 2 ] (pyCN = isonicotinonitrile)
Author(s) -
Li Dacheng,
Liu Daojie
Publication year - 2003
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.441
Subject(s) - chemistry , cadmium , octahedron , crystallography , ion , atom (system on chip) , octahedral molecular geometry , stereochemistry , crystal structure , organic chemistry , computer science , embedded system
Abstract The title compound, [Cd(SeCN) 2 (pyCN) 2 ] ∞ , adopts an extended one‐dimensional chain structure in which the neighboring cadmium atoms are bridged by two selenocyanate ions. The central cadmium atom has a distorted octahedral geometry defined by two isonicotinonitrile and four selenocyanate ions in a 4 N 2 Se fashion. Copyright © 2003 John Wiley & Sons, Ltd.