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Chiral S‐stannyl dithiophosphates and dithiophosphonates on the basis of monoterpenols
Author(s) -
Nizamov Ilyas S.,
Yakovlev Andrey A.,
Nizamov Ilnar D.,
Terenzhev Dmitriy A.,
Ivshin Kamil A.,
Kataeva Olga N.,
Shulaeva Marina P.,
Pozdeev Oscar K.,
Batyeva Elvira S.,
Cherkasov Rafael A.
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4320
Subject(s) - chemistry , ammonium , substituent , stannane , medicinal chemistry , ammonia , organic chemistry
Chiral S‐tributylstannyl dithiophosphates and dithiophosphonates were obtained by the reactions of optically active dithiophosphoric and dithiophosphonic acids containing ( S )‐(–)‐menthyl and ( R )‐(+)‐menthyl substituents with gaseous ammonia and tributyl chlorostannane. The reactions of chiral ammonium dithiophosphate containing (1 R )‐ endo ‐(+)‐fenchyl substituent with tributyl chlorostannane or tetrachlorostannane result in corresponding S‐tributylstannyl dithiophosphate or tetrakis(dithiophosphato)stannane. Molecular structure of ammonium O,O‐di‐(–)‐menthyldithiophosphate was studied by X‐ray single crystal diffraction. Bactericidal activity of S‐tributylstannyl dithiophosphates was tested.