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Mechanochemical conversion of nano potassium hydrogen terephthalate to thallium analogue nanoblocks with strong hydrogen bonding and straight chain metalophillic interactions
Author(s) -
Mirzadeh Elham,
Akhbari Kamran,
White Jonathan
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4313
Subject(s) - chemistry , hydrogen bond , coordination polymer , octahedron , metal , crystal structure , hydrogen , crystallography , polymer , oxygen atom , inorganic chemistry , ion , thallium , molecule , organic chemistry
Irreversible mechanochemical conversion of three‐dimensional K I coordination polymer [K( μ 6 ‐HTA)] n ( 1 ), [H 2 TA = terephetalic acid], prepared by sonochemical procedure, to Tl I analogue coordination polymer nanoblocks was studied. The structure of [Tl( μ 3 ‐HTA)] n ( 2 ) is exactly the same as 1 and the Tl ion has distorted octahedral coordination. The carbonyl oxygen is coordinated to two different metal ions, while another oxygen atom is bonded to one metal and participates in a very strong hydrogen bond. Both compounds have secondary straight chain metallophilic interactions. In addition to the same structures of 1 and 2 , the same crystal data of them also approved that the chemistry of thallium(I) parallels that of the potassium(I) in many ways.