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Water Soluble Benzimidazole Containing Ionic Palladium(II) Complex for Rapid Microwave‐Assisted Suzuki Reaction of Aryl Chlorides
Author(s) -
Şengül Abdurrahman,
Hanhan Murat Emre
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4288
Subject(s) - benzimidazole , chemistry , palladium , suzuki reaction , aryl , ionic bonding , ionic liquid , homogeneous , microwave heating , filtration (mathematics) , inorganic chemistry , microwave , polymer chemistry , organic chemistry , catalysis , ion , alkyl , physics , quantum mechanics , thermodynamics , statistics , mathematics
In this paper a water soluble benzimidazole – Pd complex used for Suzuki reaction under conventional heating and microwave heating. To increase the activity of complex, ionic group change with bulky TBA + and Bmim + groups. To determine whether the reaction is homogeneous or heterogeneous, Hg(0) poisoning tests, hot filtration tests and CS 2 poisoning tests were performed.