Substitution chemistry of sterically demanding boryl ligands | Zendy

Coombs Deborah L. | Zendy; Aldridge Simon | Zendy; Jones Cameron | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Substitution chemistry of sterically demanding boryl ligands

Author(s) -

Coombs Deborah L.,

Aldridge Simon,

Jones Cameron

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.426

Subject(s) - chemistry , steric effects , boron , substitution reaction , nucleophilic substitution , medicinal chemistry , substitution (logic) , aryl , nucleophilic aromatic substitution , stereochemistry , nucleophile , organic chemistry , catalysis , alkyl , computer science , programming language

The synthetic and reaction chemistry of the asymmetric aryl(bromo)boryl complexes (η 5 ‐C 5 H 5 )Fe(CO) 2 B(Ar)Br [Ar = 2,4,6‐Me 3 C 6 H 2 , Mes (3); 2,6‐(2,4,6‐ i Pr 3 C 6 H 2 )C 6 H 3 , 2,6‐Trip 2 C 6 H 3 (4)] are reported. In particular, the scope for substitution at boron by main‐group nucleophiles is probed. The synthesis and characterization of (η 5 ‐C 5 H 5 )Fe(CO) 2 B(Mes)ER n [ER n = O t Bu, (5); ER n = SPh (6)] confirm that substitution at boron can be accomplished with retention of the FeB bond. Copyright © 2003 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research