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The reduction of 4‐nitrophenol and 2‐nitroaniline by palladium catalyst based on a KCC‐1/IL in aqueous solution
Author(s) -
Baghbamidi Sakineh Esfandiari,
Hassankhani Asadollah,
Sanchooli Esmael,
Sadeghzadeh Seyed Mohsen
Publication year - 2018
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4251
Subject(s) - chemistry , catalysis , 4 nitrophenol , palladium , ionic liquid , aqueous solution , nitroaniline , selective catalytic reduction , ionic bonding , nitrophenol , homogeneous , substrate (aquarium) , chemical engineering , nanoparticle , nuclear chemistry , organic chemistry , ion , physics , oceanography , engineering , thermodynamics , geology
KCC‐1/IL/Pd NPs can used as an excellent support for the synthesis of highly sparse homogeneous catalyst. KCC‐1 has high surface area that was functionalized with ionic liquid phase acting as the strong performers so that the Pd catalyst was well‐dispersed without aggregation on the framework of the KCC‐1/IL. This nano catalyst was specified by TGA, XRD, TEM, SEM, FT‐IR, and ICP. For reduction of 2‐nitroaniline and 4‐nitrophenol used from the KCC‐1/IL/Pd NPs as a green catalyst that showed excellent catalytic activities. Compared with the traditional substrate, KCC‐1 substantially increases protection and the accessibility of the nanoparticle sites due to its three dimensional hierarchical structure.