Crystallographic report:  (4,4′‐Bipyridine)bis[bis( N , N ‐diethyldithiocarbamato)zinc(II)] | Zendy

Lai Chian Sing | Zendy; Tiekink Edward R. T. | Zendy

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Crystallographic report: (4,4′‐Bipyridine)bis[bis( N , N ‐diethyldithiocarbamato)zinc(II)]

Author(s) -

Lai Chian Sing,

Tiekink Edward R. T.

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.421

Subject(s) - chemistry , dithiocarbamate , zinc , square pyramidal molecular geometry , crystallography , trigonal bipyramidal molecular geometry , denticity , bipyramid , molecule , coordination geometry , atom (system on chip) , trigonal pyramidal molecular geometry , crystal structure , pentagonal bipyramidal molecular geometry , stereochemistry , hydrogen bond , organic chemistry , computer science , embedded system

The structure of [Zn(S 2 CNEt 2 ) 2 ] 2 (4,4′‐bipy) shows two independent dimeric molecules, one located about a centre of inversion, the other lying on a two fold axis containing the zinc atoms. Bidentate coordination by the dithiocarbamate ligands and a distorted square pyramidal geometry are found for two of zinc atoms whereas for the third zinc atom, the geometry is intermediate between square pyramidal and trigonal bipyramidal, a result that underscores the flexibility of coordination in these systems. Copyright © 2003 John Wiley & Sons, Ltd.

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