Silver sequestration of halides for the activation of Pd(OAc) 2  catalyzed Mizoroki‐Heck reaction of 1,1 and 1,2 ‐ Disubstituted alkenes | Zendy

Bangar Pronnoy G. | Zendy; Jawalkar Priyanka R. | Zendy; Dumbre Swapnil R. | Zendy; Patil Dharmaraj J. | Zendy; Iyer Suresh | Zendy

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Silver sequestration of halides for the activation of Pd(OAc) 2 catalyzed Mizoroki‐Heck reaction of 1,1 and 1,2 ‐ Disubstituted alkenes

Author(s) -

Bangar Pronnoy G.,

Jawalkar Priyanka R.,

Dumbre Swapnil R.,

Patil Dharmaraj J.,

Iyer Suresh

Publication year - 2018

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.4159

Subject(s) - chemistry , catalysis , aryl , halide , stoichiometry , palladium , ligand (biochemistry) , medicinal chemistry , heck reaction , organic chemistry , alkyl , receptor , biochemistry

A ligand free catalytic system consisting of Pd(OAc) 2 (cat) and stoichiometric quantities of silver salts, AgOAc or AgBF 4 , exhibit high efficiency in the Mizoroki‐Heck arylation, transforming aryl iodides and 1,1 as well as 1,2 disubstituted alkenes into 1,1,2 – trisubstituted aryl alkenes in excellent yields in very short reaction times.

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