Microporous assembly and shape control of a new Zn metal–organic framework: Morphology‐dependent catalytic performance | Zendy

Wang Jiajia | Zendy; Han Yuqing | Zendy; Xu Haitao | Zendy; Xu ZhenLiang | Zendy

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Microporous assembly and shape control of a new Zn metal–organic framework: Morphology‐dependent catalytic performance

Author(s) -

Wang Jiajia,

Han Yuqing,

Xu Haitao,

Xu ZhenLiang

Publication year - 2018

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.4097

Subject(s) - microporous material , chemistry , catalysis , metal organic framework , porosity , nanotechnology , chemical engineering , flexibility (engineering) , metal , microsphere , morphology (biology) , organic chemistry , materials science , statistics , mathematics , adsorption , biology , engineering , genetics

A new metal–organic framework (MOF), [Zn(ATA)(bpd)] ∝ ( 1Zn ) (ATA: 2‐aminoterephthalic acid; bpd: 1,4‐bis(4‐pyridyl)‐2,3‐diaza‐1,3‐butadiene), exhibiting a three‐dimensional extended porous structure was successfully assembled in a MeOH–H 2 O solvent system. Under various controlled conditions, 1Zn was obtained in a variety of morphologies such as microspheres, microblocks, microsheets, microplates and microrods. The catalytic performance of the 1Zn microsized MOF was evaluated, and a possible catalytic mechanism was proposed. The flexibility of this MOF assembly strategy for shape control will certainly enhance new potential applications of micro−/nano−MOFs.

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