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Iron oxide on carbon‐based supports as efficient catalysts for organic compounds oxidation
Author(s) -
Amini Mojtaba,
Najafpour Mohammad Mahdi,
Salimi Saeideh,
Ramezani Sakine,
Ashouri Fatemeh,
Mahmoudi Ghodrat
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3892
Subject(s) - chemistry , catalysis , fourier transform infrared spectroscopy , inorganic chemistry , x ray photoelectron spectroscopy , carbon nanotube , sulfoxide , infrared spectroscopy , oxide , reactivity (psychology) , photochemistry , organic chemistry , chemical engineering , nanotechnology , materials science , engineering , medicine , alternative medicine , pathology
For the first time, iron oxide on carbon aerogel, amine functionalized carbon nanotube, black carbon and carboxylic acid functionalized carbon nanotube in the presence of H 2 O 2 was reported as an efficient and stable catalyst for the selective oxidation of sulfides and alcohols. The catalysts were characterized by scanning electron microscopy, energy‐dispersive spectroscopy, transmission electron microscopy, X‐ray photoelectron spectroscopy, X‐ray diffraction, Fourier transform infrared spectroscopy and atomic absorption spectroscopy. In the next step, catalytic reactivity toward sulfide to sulfoxide and alcohol to aldehyde/ketone oxidation in the presence of H 2 O 2 was studied and discussed.