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Magnetic GO‐PANI decorated with Au NPs: A highly efficient and reusable catalyst for reduction of dyes and nitro aromatic compounds
Author(s) -
Pourjavadi Ali,
Doroudian Mohadeseh,
AbedinMoghanaki Azardokht,
Bennett Craig
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3881
Subject(s) - catalysis , chemistry , rhodamine b , graphene , nitro , high resolution transmission electron microscopy , polyaniline , methylene blue , oxide , nanoparticle , chemical engineering , x ray photoelectron spectroscopy , phenol , inorganic chemistry , photocatalysis , organic chemistry , transmission electron microscopy , polymer , polymerization , alkyl , engineering
Due to the high activity of Au nanoparticles (NPs) for various reactions, many researchers have tried to develop heterogeneous catalysts in order to prevent irreversible agglomeration of Au NPs. Herein, magnetic graphene oxide modified with polyaniline (PANI) was used as a support for Au NPs that brings together advantages including: uniform dispersal of the catalyst in water,alarge surface area related to the graphene oxide; easy electron transfer in chemical reactions and good attachment of Au NPs to the support associated with PANI; and finally facile recovery in the presence of a magnetic field. Catalytic reduction of different analytes (Congo red, methylene blue, rhodamine B and 4‐nitro phenol) was evaluated in the presence of NaBH 4 and the results show high catalytic activity of the catalyst. The catalyst was thoroughly characterized using various methods including FTIR, XRD, XPS, FE‐SEM and HRTEM analyses while its catalytic activity was evaluated via reduction of different analytes.