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Heterogeneous Jacobsen's catalyst on alkoxyl‐modified zirconium poly (styrene‐phenylvinylphosphonate)‐phosphate (ZPS‐PVPA) for asymmetric epoxidation
Author(s) -
Huang Jing,
Ding Weigang,
Cai Jiali
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3861
Subject(s) - chemistry , alkoxy group , styrene , catalysis , zirconium , polymer chemistry , organic chemistry , copolymer , polymer , alkyl
Chiral Jacobsen's catalysts grafted onto alkoxyl‐modified ZPS‐PVPA exhibit excellent activities (conv%, up to 96; sele%, up to 96; ee%, up to >99) in the asymmetric epoxidations of unfunctionalized olefins. The superior stabilities and the comfortable dispositions in large‐scale reactions contribute to the potential applications in industry.