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Crystallographic report: Bis(pyrrolinedithiocarbamato)mercury(II)
Author(s) -
Lai Chian Sing,
Tiekink Edward R. T.
Publication year - 2003
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.383
Subject(s) - dithiocarbamate , chemistry , mercury (programming language) , crystallography , tetrahedron , chelation , bond length , crystal structure , stereochemistry , inorganic chemistry , organic chemistry , computer science , programming language
The mononuclear structure of Hg(S 2 CN(CH 2 ) 4 ) 2 has crystallographically imposed twofold symmetry and features chelating dithiocarbamate ligands that form asymmetric HgS bond distances leading to a heavily distorted tetrahedral geometry. Copyright © 2003 John Wiley & Sons, Ltd.