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Iron‐catalyzed carbon–sulfur bond formation: Atom‐economic construction of thioethers with diaryliodonium salts
Author(s) -
Liu Li,
Qiang Jian,
Bai Shuhua,
Li Yang,
Li Jian
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3810
Subject(s) - chemistry , sulfur , catalysis , atom (system on chip) , carbon atom , carbon fibers , atom economy , polymer chemistry , organic chemistry , ring (chemistry) , materials science , composite number , computer science , composite material , embedded system
Diaryliodonium salts are characterized by poor atom economy with the formation of one equivalent of an iodoarene as waste. We have developed an atom‐economic iron‐catalyzed protocol for the synthesis of a variety of thioethers with diaryliodonium salts. Not only cyclic diaryliodonium salts but also linear diaryliodonium salts were found to perform well in the reactions.