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Manganese(II) tetrasulfophthalocyanine covalently supported on natural silk: A new highly active catalyst for synthesis of benzoxazepine derivatives in water
Author(s) -
Hezarkhani Zeinab,
Faroghi Mohammad Tayeb,
Shaabani Ahmad
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3764
Subject(s) - chemistry , covalent bond , silk , manganese , catalysis , polymer chemistry , ligand (biochemistry) , reusability , organic chemistry , combinatorial chemistry , biochemistry , receptor , software , computer science , programming language , operating system
Natural silk as a biodegradable, biocompatible, renewable, green and abundant biomaterial was used as a support for chemical immobilization of a water‐soluble manganese(II) complex with a phthalocyanine ligand possessing covalent binding ability. The prepared manganese(II) tetrasulfophthalocyanine complex supported on natural silk revealed efficient catalytic activity and reusability for the synthesis of benzoxazepine derivatives in water at room temperature.