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Self‐assembled Pd nanoparticle‐containing ionic liquid: Efficient and reusable catalyst for the Heck reaction in water
Author(s) -
Zong Yingxiao,
Wang Junke,
An Pengli,
Yue Guoren,
Pan Yi,
Wang Xicun
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3762
Subject(s) - chemistry , catalysis , heck reaction , ionic liquid , palladium , nanoparticle , fourier transform infrared spectroscopy , solvent , polymer , heterogeneous catalysis , chemical engineering , polymer chemistry , nuclear chemistry , inorganic chemistry , organic chemistry , engineering
A self‐assembled Pd nanoparticle‐containing ionic liquid as metal–organic polymer was successfully prepared. The structure of the catalyst was characterized using Fourier transform infrared and 1 H NMR spectroscopies, scanning electron microscopy and elemental analysis. The catalyst was effectively employed in the palladium‐catalyzed Heck reaction in water as a green solvent. Moreover, due to its stability the catalyst can be recovered simply and effectively and reused nine times without much loss of activity.