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An efficient and recoverable palladium organocatalyst for Suzuki reaction in aqueous media
Author(s) -
FareghiAlamdari Reza,
Golestanzadeh Mohsen,
Bagheri Omid
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3698
Subject(s) - chemistry , phenylboronic acid , palladium , catalysis , aryl , aqueous medium , aqueous solution , suzuki reaction , halide , coupling reaction , organic chemistry , reusability , solvent , combinatorial chemistry , boronic acid , alkyl , software , computer science , programming language
Meso‐tetrakis[4‐(methoxycarbonyl)phenyl]porphyrinatopalladium(II) as a palladium organocatalyst was synthesized and then used in aqueous media as a heterogeneous organocatalyst in Suzuki reaction. The prepared organocatalyst was characterized using UV–visible, infrared and NMR spectroscopies. It was found to be an efficient catalyst for Suzuki coupling reaction between phenylboronic acid and a broad range of aryl halides. Mild reaction conditions, water solvent as green media, and easy catalyst separation and reusability are the advantages of the presented method.