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Synthesis and characterization of bromine source immobilized on diethylenetriamine‐functionalized magnetic nanoparticles: A novel, versatile and highly efficient reusable catalyst for organic synthesis
Author(s) -
Shiri Lotfi,
Rahmati Sadegh,
Ramezani Nejad Zahra,
Kazemi Mosstafa
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3687
Subject(s) - thermogravimetric analysis , catalysis , chemistry , knoevenagel condensation , diethylenetriamine , bromine , fourier transform infrared spectroscopy , nanoparticle , magnetic nanoparticles , nuclear chemistry , organic chemistry , polymer chemistry , chemical engineering , nanotechnology , materials science , engineering
Bromine source immobilized on magnetic nanoparticles functionalized with diethylenetriamine was successfully synthesized and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, vibrating sample magnetometry, thermogravimetric analysis and X‐ray diffraction. The catalytic activity in the synthesis of 2,3‐dihydroquinazoline‐4(1 H )‐one and polyhydroquinoline derivatives and in Knoevenagel condensation was studied. The bromine catalyst can be magnetically recovered and reused several times without significant loss of its catalytic activity. All products were obtained in high to excellent yields.