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Carbofunctional sulfur‐containing organosilicon compounds
Author(s) -
Vlasova N.N.,
Sorokin M.S.,
Oborina E.N.
Publication year - 2017
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3668
Subject(s) - organosilicon , chemistry , polysulfide , sulfur , alkyl , organic chemistry , aryl , sulfide , flammable liquid , hypervalent molecule , polymer chemistry , electrolyte , electrode , reagent
This review summarizes literature data and the authors’ own research results from the past 14–15 years relating to practical, valuable organosilicon carbofunctional sulfur‐containing compounds of general formula R 4− n Si(S x R 1 ) n , where R is alkyl, arylalkoxyl, aroxyl or even sylatranyl fragment, R 1 is hydrogen, alkyl, aryl, alkenyl, etc., n = 1–3, x = 1–10, having sulfur functional groups such as thiol, sulfide, di‐ and polysulfide, as well as sulfur heteroatomic groups such as thiocarbamide, dioxothiocarbamide, dithiourethane, thiuramdisulfide, etc. The compounds reviewed have been found to be effective, for example, as ingredients for rubber compositions for non‐flammable, water‐ and wear‐proof tires or as ion‐exchanging and complexing sorbents of heavy and noble metals.