Crystallographic report: 1,3‐Bis[(trimethylsilylmethyl)dichlorostannyl]propane, [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3 | Zendy

Dakternieks Dainis | Zendy; Kuan Fong Sheen | Zendy; Duthie Andrew | Zendy; Tiekink Edward R. T. | Zendy

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Crystallographic report: 1,3‐Bis[(trimethylsilylmethyl)dichlorostannyl]propane, [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3

Author(s) -

Dakternieks Dainis,

Kuan Fong Sheen,

Duthie Andrew,

Tiekink Edward R. T.

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.363

Subject(s) - chemistry , crystallography , intermolecular force , tin , propane , molecule , tetrahedron , distortion (music) , x ray crystallography , stereochemistry , diffraction , physics , organic chemistry , amplifier , cmos , optoelectronics , optics

The dinuclear molecule of [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3 adopts an extended conformation and features distorted tetrahedral tin centres, with the greatest distortion manifested in the CSnC angles of approximately 128 °. The distortions are ascribed to the influence of intermolecular Sn···Cl interactions. Copyright © 2002 John Wiley & Sons, Ltd.

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