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Crystallographic report: 1,3‐Bis[(trimethylsilylmethyl)dichlorostannyl]propane, [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3
Author(s) -
Dakternieks Dainis,
Kuan Fong Sheen,
Duthie Andrew,
Tiekink Edward R. T.
Publication year - 2003
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.363
Subject(s) - chemistry , crystallography , intermolecular force , tin , propane , molecule , tetrahedron , distortion (music) , x ray crystallography , stereochemistry , diffraction , physics , organic chemistry , amplifier , cmos , optoelectronics , optics
The dinuclear molecule of [(Me 3 SiCH 2 )Cl 2 Sn] 2 (CH 2 ) 3 adopts an extended conformation and features distorted tetrahedral tin centres, with the greatest distortion manifested in the CSnC angles of approximately 128 °. The distortions are ascribed to the influence of intermolecular Sn···Cl interactions. Copyright © 2002 John Wiley & Sons, Ltd.