Metal–organic framework of amine‐MIL‐53(Al) as active and reusable liquid‐phase reaction inductor for multicomponent condensation of  Ugi‐type reactions | Zendy

Rostamnia Sadegh | Zendy; Jafari Maryam | Zendy

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Metal–organic framework of amine‐MIL‐53(Al) as active and reusable liquid‐phase reaction inductor for multicomponent condensation of Ugi‐type reactions

Author(s) -

Rostamnia Sadegh,

Jafari Maryam

Publication year - 2017

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3584

Subject(s) - chemistry , amine gas treating , isocyanide , aldehyde , yield (engineering) , condensation reaction , condensation , solvent , metal , phase (matter) , organic synthesis , organic chemistry , combinatorial chemistry , polymer chemistry , catalysis , materials science , physics , metallurgy , thermodynamics

Metal–organic framework of NH 2 ‐MIL‐53(Al), with coordinative unsaturated aluminium sites, has been shown to be active in the Groebke–Blackburn–Bienaymé multicomponent coupling reaction based on Ugi‐type amine and aldehyde condensation over isocyanide and then a cyclization process. Interestingly this reaction occurred under solvent‐free conditions with high yield, in which the NH 2 ‐MIL‐53(Al) could be recovered and reused for five reaction cycles, giving a total turnover number of 455.

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