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Water–gas shift reaction catalyzed by mononuclear ruthenium complexes containing bipyridine and phenanthroline derivatives
Author(s) -
Aguirre Pedro,
Moya Sergio A.,
Sariego Renato,
Bozec Hubert Le,
Pardey Alvaro J.
Publication year - 2002
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.353
Subject(s) - chemistry , ruthenium , phenanthroline , triethylamine , catalysis , 2,2' bipyridine , derivative (finance) , medicinal chemistry , water gas shift reaction , aqueous solution , trimethylamine , bipyridine , aqueous medium , polymer chemistry , organic chemistry , financial economics , crystal structure , economics
Ruthenium complexes of the type [RuL(CO) 2 Cl 2 ], [RuL 2 Cl 2 ], [RuL 2 (CO)(H 2 O)](PF 6 ) 2 , [RuL 2 Cl] 2 (PF 6 ) 2 , [RuL 2 (CO)Cl](PF 6 ), and [RuL 2 (CO 3 )]·3H 2 O (where L is a bipyridine or phenanthroline derivative) dissolved in aqueous 2‐ethoxyethanol, and in a basic medium of KOH, triethylamine, or trimethylamine, catalyze the water‐gas shift reaction under mild conditions (P CO = 0.9 atm at 100 °C). Copyright © 2002 John Wiley & Sons, Ltd.