First report of a nano‐Cu 2 O‐catalyzed protocol for homo‐coupling reaction of terminal alkynes in water/ionic liquid medium | Zendy

Tang BoXiao | Zendy; Fang XiaoNiu | Zendy; Kuang RenYun | Zendy; Wu JianHong | Zendy; Chen Qiao | Zendy; Hu ShaoJun | Zendy; Liu YiLin | Zendy

Premium

First report of a nano‐Cu 2 O‐catalyzed protocol for homo‐coupling reaction of terminal alkynes in water/ionic liquid medium

Author(s) -

Tang BoXiao,

Fang XiaoNiu,

Kuang RenYun,

Wu JianHong,

Chen Qiao,

Hu ShaoJun,

Liu YiLin

Publication year - 2016

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3525

Subject(s) - chemistry , catalysis , ionic liquid , terminal (telecommunication) , copper , solvent , coupling reaction , nano , ionic bonding , coupling (piping) , environmentally friendly , reaction conditions , combinatorial chemistry , polymer chemistry , chemical engineering , organic chemistry , ion , metallurgy , telecommunications , materials science , computer science , engineering , ecology , biology

A new, efficient and green protocol for the nano‐Cu 2 O‐catalyzed homo‐coupling reaction of terminal alkynes has been developed, using water/ionic liquid as an environmentally friendly solvent. Moreover, the system also allows the synthesis of unsymmetric 1,3‐diynes by cross‐coupling of two different terminal alkynes. It is noteworthy that the nano‐Cu 2 O‐catalyzed methodology is a good supplement to copper catalyst for the Glaser‐type homo‐coupling reaction. Copyright © 2016 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research