Ruthenium(II) complexes derived from 2‐phenylthiazoline‐4‐carboxylic acid: structure and  catalytic activity  for  transfer hydrogenation  reaction | Zendy

Denizaltı Serpil | Zendy; Şen Betül | Zendy; Gökçe Aytaç Gürhan | Zendy; Çetinkaya Bekir | Zendy

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Ruthenium(II) complexes derived from 2‐phenylthiazoline‐4‐carboxylic acid: structure and catalytic activity for transfer hydrogenation reaction

Author(s) -

Denizaltı Serpil,

Şen Betül,

Gökçe Aytaç Gürhan,

Çetinkaya Bekir

Publication year - 2016

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3442

Subject(s) - ruthenium , chemistry , transfer hydrogenation , isopropyl alcohol , catalysis , carboxylic acid , alcohol , medicinal chemistry , isopropyl , organic chemistry

Piano‐stool ([( p ‐cymene)Ru(thz)Cl], 2 ) and six‐coordinated ([Ru(thz) 2 (PPh 3 ) 2 ], 3 ) ruthenium complexes derived from 2‐phenylthiazoline‐4‐carboxylic acid (Hthz, 1 ) were synthesized for the first time, and fully characterized using conventional methods. Also, the molecular structure of complex 3 was determined using X‐ray analysis. These complexes were evaluated as catalysts for transfer hydrogenation of carbonyl compounds in the presence of isopropyl alcohol and KO t Bu. Complex 2 was found to be more active than 3 in transfer hydrogenation . Copyright © 2016 John Wiley & Sons, Ltd.

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