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Assembly of homoallylamine derivatives through iron‐catalyzed three‐component sulfonamidoallylation reaction
Author(s) -
Fan Xiaohui,
Zhu HongBo,
Lv Hao,
Guo Kun,
Guan YongHong,
Cui XiaoMeng,
An Bin,
Pu YanLing
Publication year - 2015
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3334
Subject(s) - chemistry , catalysis , stereoselectivity , component (thermodynamics) , atom economy , reaction conditions , atom (system on chip) , combinatorial chemistry , organic chemistry , thermodynamics , embedded system , physics , computer science
An efficient FeCl 3 ‐catalyzed three‐component reaction between aldehydes, sulfonamides and allylsilanes has been achieved, which provides a convenient, atom‐economic and green way to construct homoallylamine derivatives. In addition, this reaction exhibits excellent syn stereoselectivity with γ‐substituted allylsilanes.