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An expedient approach to enhance Mizoroki–Heck coupling reaction by infrared irradiation using palladacycle compounds
Author(s) -
OrtegaJiménez Fernando,
DomínguezVilla Francisco X.,
RosasSánchez Alfredo,
PenieresCarrillo Guillermo,
LópezCortés José G.,
OrtegaAlfaro M. Carmen
Publication year - 2015
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3331
Subject(s) - chemistry , yield (engineering) , heck reaction , coupling reaction , coupling (piping) , palladium , combinatorial chemistry , irradiation , infrared , organic chemistry , photochemistry , catalysis , physics , mechanical engineering , materials science , optics , nuclear physics , engineering , metallurgy
An alternative and environmentally friendly strategy to promote the Mizoroki–Heck cross‐coupling reaction by the use of infrared irradiation using palladacycles as precatalysts is reported. Coupling products are obtained in high yield and short reaction time. A comparison with the classical use of reflux conditions, and commercial sources of palladium complexes, shows the advantages of this new alternative for promoting coupling reactions . Copyright © 2015 John Wiley & Sons, Ltd.