Pd(II) complexes of Schiff bases and their application as catalysts in Mizoroki–Heck and  Suzuki–Miyaura cross‐coupling reactions | Zendy

Keleş Mustafa | Zendy; Keleş Hülya | Zendy; Emir Duygu Melis | Zendy

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Pd(II) complexes of Schiff bases and their application as catalysts in Mizoroki–Heck and Suzuki–Miyaura cross‐coupling reactions

Author(s) -

Keleş Mustafa,

Keleş Hülya,

Emir Duygu Melis

Publication year - 2015

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3329

Subject(s) - chemistry , palladium , catalysis , heck reaction , cyclic voltammetry , aniline , dimethylformamide , electrochemistry , coupling reaction , polymer chemistry , carbon 13 nmr , medicinal chemistry , organic chemistry , inorganic chemistry , electrode , solvent

Schiff bases of 2‐(phenylthio)aniline, (C 6 H 5 )SC 6 H 4 NCR (R = ( o ‐CH 3 )(C 6 H 5 ), ( o ‐OCH 3 )(C 6 H 5 ) or ( o ‐CF 3 )(C 6 H 5 )), and their palladium complexes (PdLCl 2 ) were synthesized. The compounds were characterized using 1 H NMR and 13 C NMR spectroscopy and micro analysis. Also, electrochemical properties of the ligands and Pd(II) complexes were investigated in dimethylformamide–LiClO 4 solution with cyclic and square wave voltammetry techniques. The Pd(II) complexes showed both reversible and quasi‐reversible processes in the −1.5 to 0.3 V potential range. The synthesized Pd(II) complexes were evaluated as catalysts in Mizoroki–Heck and Suzuki–Miyaura cross‐coupling reactions . Copyright © 2015 John Wiley & Sons, Ltd.

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