Palladium supported on silica–chitosan hybrid material (Pd‐CS@SiO 2 ) for  Suzuki–Miyaura  and Mizoroki–Heck  cross‐coupling reactions | Zendy

Jadhav Sanjay | Zendy; Kumbhar Arjun | Zendy; Salunkhe Rajashri | Zendy

Premium

Palladium supported on silica–chitosan hybrid material (Pd‐CS@SiO 2 ) for Suzuki–Miyaura and Mizoroki–Heck cross‐coupling reactions

Author(s) -

Jadhav Sanjay,

Kumbhar Arjun,

Salunkhe Rajashri

Publication year - 2015

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3290

Subject(s) - chemistry , thermogravimetric analysis , palladium , catalysis , chitosan , aryl , heck reaction , halide , coupling reaction , dimethylformamide , polymer chemistry , fourier transform infrared spectroscopy , nuclear chemistry , organic chemistry , inorganic chemistry , chemical engineering , alkyl , solvent , engineering

Palladium supported on silica–chitosan hybrid material was prepared and characterized using thermogravimetric and differential thermogravimetric analyses, scanning electron microscopy , and Fourier transform infrared, energy‐dispersive X‐ray and X‐ray photoelectron spectroscopies. The prepared Pd‐CS@SiO 2 catalyst (1 mol%) was used for the Suzuki–Miyaura cross‐coupling reaction of various aryl halides and arylboronic acids in 95% ethanol at 80 °C and the Mizoroki–Heck reaction in dimethylformamide at 110 °C using K 2 CO 3 as a base. The developed catalyst is well suitable for the 3R approach (recoverable, robust, recyclable) for cross‐coupling reactions without appreciable loss of its activity. Copyright © 2015 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research