Silver‐catalyzed Glaser  coupling of alkynes | Zendy

Mo Guoli | Zendy; Tian Zaimin | Zendy; Li Jiping | Zendy; Wen Guohua | Zendy; Yang Xiaomin | Zendy

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Silver‐catalyzed Glaser coupling of alkynes

Author(s) -

Mo Guoli,

Tian Zaimin,

Li Jiping,

Wen Guohua,

Yang Xiaomin

Publication year - 2015

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3275

Subject(s) - chemistry , triphenylphosphine , catalysis , silver nitrate , dimethylformamide , ligand (biochemistry) , combinatorial chemistry , coupling reaction , alkyne , organic chemistry , polymer chemistry , biochemistry , receptor , solvent

Excellent yields were obtained from the silver nitrate‐catalyzed homocoupling reaction of alkynes in N , N ‐dimethylformamide using triphenylphosphine as ligand. This safe and simple silver catalytic system has been employed in a safe and efficient protocol for the synthesis of various 1,3‐diyne products from the corresponding aromatic or aliphatic alkynes with good air stability and absence of side products. Copyright © 2015 John Wiley & Sons, Ltd.

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