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A versatile method for the synthesis of diaryl and alkyl aryl ketones via palladium‐catalysed cross‐coupling reaction of arylboronic acids with acyl chlorides
Author(s) -
Rafiee Fatemeh,
Hajipour Abdol R.
Publication year - 2015
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3269
Subject(s) - chemistry , catalysis , aryl , alkyl , palladium , octane , coupling reaction , organic chemistry , chloride , reaction conditions , homogeneous catalysis , combinatorial chemistry , medicinal chemistry
An efficient catalytic system using 1‐benzyl‐4‐aza‐1‐azoniabicyclo[2.2.2]octane chloride and PdCl 2 was developed for the cross‐coupling reaction of arylboronic acids with acyl chlorides. The catalytic amount of this homogeneous catalytic system affords the corresponding diaryl and alkyl aryl ketones in good to excellent yields under mild reaction conditions. Copyright © 2015 John Wiley & Sons, Ltd.