One‐pot synthesis  of polyfluoroterphenyls via palladium‐catalyzed  Suzuki–Miyaura coupling  of chlorobromobenzene and  CH bond functionalization  of perfluoroarenes | Zendy

Ma Xiaowei | Zendy; Gu Ningning | Zendy; Liu Yan | Zendy; Liu Ping | Zendy; Xie Jianwei | Zendy; Dai Bin | Zendy; Liu Zhiyong | Zendy

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One‐pot synthesis of polyfluoroterphenyls via palladium‐catalyzed Suzuki–Miyaura coupling of chlorobromobenzene and CH bond functionalization of perfluoroarenes

Author(s) -

Ma Xiaowei,

Gu Ningning,

Liu Yan,

Liu Ping,

Xie Jianwei,

Dai Bin,

Liu Zhiyong

Publication year - 2015

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3248

Subject(s) - chemistry , palladium , catalysis , tandem , surface modification , combinatorial chemistry , coupling reaction , crystal structure , cascade reaction , polymer chemistry , organic chemistry , materials science , composite material

An efficient tandem route for the synthesis of polyfluoroterphenyl derivatives has been developed. The target compounds were obtained in moderate to good yields by a Pd(OAc) 2 ‐catalyzed three‐component coupling reaction involving palladium‐catalyzed direct CH activation of perfluoroarenes. This in turn will set the stage for a wide application of this useful reaction for the synthesis of fluorinated liquid crystal compounds containing the privileged polyfluoroterphenyl structure. Copyright © 2014 John Wiley & Sons, Ltd.

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