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Pd(II) salen complex covalently anchored to multi‐walled carbon nanotubes as a heterogeneous and reusable precatalyst for Mizoroki–Heck and Hiyama cross‐coupling reactions
Author(s) -
Movassagh Barahman,
Parvis Fatemeh S.,
Navidi Mozhgan
Publication year - 2015
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3246
Subject(s) - chemistry , halide , catalysis , aryl , carbon nanotube , heck reaction , covalent bond , polymer chemistry , heterogeneous catalysis , coupling reaction , carbon fibers , combinatorial chemistry , organic chemistry , palladium , chemical engineering , alkyl , composite number , engineering , materials science , composite material
A Pd(II) salen complex anchored to multi‐walled carbon nanotubes showed excellent catalytic activity and stability for the Mizoroki–Heck and Hiyama cross‐couplings of aryl halides with olefins and phenylsiloxanes. Furthermore, the heterogeneous catalyst could be reused up to four times with the catalytic activity being recovered easily after simple manipulations. Copyright © 2014 John Wiley & Sons, Ltd.