Premium
Cu‐catalyzed coupling of arylsulfinic salts with arylsilanes under mild conditions
Author(s) -
Yang Xiaomin,
Cao Yanyan,
Li Enbo,
Zhang Pengmei,
Hou Zhanzhong
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3199
Subject(s) - chemistry , catalysis , combinatorial chemistry , nitrogen , coupling (piping) , organic chemistry , polymer chemistry , metallurgy , materials science
Arylsilanes were efficiently coupled with arylsulfinic salts for the first time under mild conditions. Diarylsulfone derivatives were easily synthesized in high yields with the assistance of nitrogen‐containing ligands and KF. The transformation is simple and efficient and the starting materials are readily available. Copyright © 2014 John Wiley & Sons, Ltd.