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Efficient cyanation of aryl halide with K 4 [Fe(CN) 6 ]⋅3H 2 O catalyzed by a P–O bidentate chelate palladium complex under air
Author(s) -
Fu Leiqing,
Li Xiaogang,
Zhu Qiming,
Chen Sanbao,
Kang Yanping,
Guo Mengping
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3185
Subject(s) - cyanation , chemistry , palladium , halide , aryl , denticity , catalysis , chelation , medicinal chemistry , aryl halide , inorganic chemistry , polymer chemistry , organic chemistry , crystal structure , alkyl
Cyanation of aryl halide with K 4 [Fe(CN) 6 ]⋅3H 2 O has been carried out in the presence of a high‐activity catalyst: an air‐stable P–O bidentate chelate palladium complex. This method is applicable to both activated and deactivated aryl halides, and even a variety of aromatic nitriles are obtained in good yields under aerobic conditions. Copyright © 2014 John Wiley & Sons, Ltd.