Efficient  cyanation  of aryl halide with K 4 [Fe(CN) 6 ]⋅3H 2 O catalyzed by a P–O bidentate chelate palladium complex under air | Zendy

Fu Leiqing | Zendy; Li Xiaogang | Zendy; Zhu Qiming | Zendy; Chen Sanbao | Zendy; Kang Yanping | Zendy; Guo Mengping | Zendy

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Efficient cyanation of aryl halide with K 4 [Fe(CN) 6 ]⋅3H 2 O catalyzed by a P–O bidentate chelate palladium complex under air

Author(s) -

Fu Leiqing,

Li Xiaogang,

Zhu Qiming,

Chen Sanbao,

Kang Yanping,

Guo Mengping

Publication year - 2014

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3185

Subject(s) - cyanation , chemistry , palladium , halide , aryl , denticity , catalysis , chelation , medicinal chemistry , aryl halide , inorganic chemistry , polymer chemistry , organic chemistry , crystal structure , alkyl

Cyanation of aryl halide with K 4 [Fe(CN) 6 ]⋅3H 2 O has been carried out in the presence of a high‐activity catalyst: an air‐stable P–O bidentate chelate palladium complex. This method is applicable to both activated and deactivated aryl halides, and even a variety of aromatic nitriles are obtained in good yields under aerobic conditions. Copyright © 2014 John Wiley & Sons, Ltd.

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