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Ligand‐free Pd/Cu‐catalyzed decarboxylative coupling of aryl iodides with α‐oxocarboxylates
Author(s) -
Ji Yongfeng,
Yang Xiaomin,
Mao Weixi
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3181
Subject(s) - chemistry , aryl , catalysis , palladium , ligand (biochemistry) , decarboxylation , coupling (piping) , combinatorial chemistry , copper , coupling reaction , organic chemistry , receptor , alkyl , mechanical engineering , biochemistry , engineering
This paper describes a palladium/copper‐catalyzed decarboxylative coupling of aryl iodides with α‐oxocarboxylates. The cross‐coupling reaction gives high chemical yields of aryl ketones and has wide functional group tolerance, making the transformation an attractive alternative to the traditional cross‐coupling approaches for aryl ketones. Copyright © 2014 John Wiley & Sons, Ltd.