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Chemoselective one‐pot synthesis of terphenyl derivatives by sequential directed C―H functionalization–Suzuki coupling
Author(s) -
Ren Limin,
Chu Wenyi,
Guan Dinghui,
Hou Yanjun,
Wang Man,
Yuan Xiaobin,
Sun Zhizhong
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3180
Subject(s) - chemistry , terphenyl , cyclohexane , palladium , yield (engineering) , combinatorial chemistry , suzuki reaction , ligand (biochemistry) , organic chemistry , coupling reaction , catalysis , surface modification , biochemistry , materials science , receptor , metallurgy
A simple and efficient route for the preparation of terphenyl derivatives via palladium‐catalyzed sequential directed C―H arylation/Suzuki–Miyaura cross‐coupling in ‘one‐pot’ has been developed. 4,4′‐(Cyclohexane‐1,1‐diyl)diphenol is an essential ligand. This reaction can tolerate a series of functional groups and provides the terphenyl derivatives in moderate to good yield. Copyright © 2014 John Wiley & Sons, Ltd.