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Synthesis, characterization and catalytic activity of Pd(II) complexes with N ‐allyl functionalized imidazol‐2‐ylidenes in Suzuki–Miyaura reaction
Author(s) -
Gümüşada Rukiye,
Özdemir Namık,
Günay M. Emin,
Dinçer Muharrem,
Soylu Mustafa Serkan,
Çetinkaya Bekir
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3128
Subject(s) - phenylboronic acid , chemistry , aryl , carbene , catalysis , palladium , suzuki reaction , medicinal chemistry , polymer chemistry , elemental analysis , organic chemistry , alkyl
A series of Pd– N ‐heterocyclic carbene (Pd–NHC) complexes were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structures of 3c and 4c were determined by X‐ray diffraction studies. Finally, the performance of complexes 3 and 5 were studied on Suzuki–Miyaura reactions of phenylboronic acid with aryl bromides. Copyright © 2014 John Wiley & Sons, Ltd.