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Sn‐mediated one‐pot four‐component allylation of aldimines
Author(s) -
Li Jian,
Lv Wenxian,
Huang Danfeng,
Wang KeHu,
Niu Teng,
Su Yingpeng,
Hu Yulai
Publication year - 2014
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3122
Subject(s) - chemistry , aldimine , allylic rearrangement , yield (engineering) , bromide , tin , organic chemistry , one pot synthesis , combinatorial chemistry , catalysis , materials science , metallurgy
A convenient and facile method for the synthesis of homoallylic amines was disclosed. The one‐pot reaction of aldehydes, aromatic amines and allylic bromide with tin powder at room temperature could afford the homoallylic amines in good to excellent yield without any promoter or additive. The method is highly efficient and environmentally benign with low cost and concise manipulation. Copyright © 2014 John Wiley & Sons, Ltd.