Synthesis, structural characterization and  catalytic activity  of benzimidazole‐functionalized Pd(II)  N ‐heterocyclic carbene complexes | Zendy

Diao Yalin | Zendy; Hao Rong | Zendy; Kou Junfeng | Zendy; Teng Mingyu | Zendy; Huang Guoli | Zendy; Chen Yegao | Zendy

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Synthesis, structural characterization and catalytic activity of benzimidazole‐functionalized Pd(II) N ‐heterocyclic carbene complexes

Author(s) -

Diao Yalin,

Hao Rong,

Kou Junfeng,

Teng Mingyu,

Huang Guoli,

Chen Yegao

Publication year - 2013

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.3030

Subject(s) - benzimidazole , chemistry , carbene , palladium , pyridine , catalysis , aryl , halide , medicinal chemistry , combinatorial chemistry , coupling reaction , polymer chemistry , stereochemistry , organic chemistry , alkyl

Two Pd(II)–NHC complexes bearing benzimidazole and pyridine groups have been successfully prepared and fully characterized by NMR and X‐ray diffraction analysis. The structure of palladium complexes are a typical square‐planar with palladium surrounded by two pairs of trans ‐arranged benzimidazole and carbene ligands. The Pd–NHC complexes have been proved to be a highly efficient catalyst for the Mizoroki–Heck coupling reaction of aryl halides with various substituted acrylates under mild conditions in excellent yields. Copyright © 2013 John Wiley & Sons, Ltd.

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