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Metallomicelles of palladium(II) complexes as efficient catalysts for the Suzuki–Miyaura reaction in neat water
Author(s) -
Liu Yan,
Ma Xiaowei,
Xie Jianwei,
Liu Ping,
Dai Bin,
He Ren
Publication year - 2013
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.3021
Subject(s) - chemistry , catalysis , palladium , alkyl , aryl , biphenyl , organic chemistry , suzuki reaction , combinatorial chemistry , polymer chemistry
Metallomicelles of palladium(II) complex 4 are found to be an efficient catalyst for Suzuki–Miyaura reactions of aryl bromides substituted with a long alkyl chain and arylboronic acids at 80 °C in neat water. The reactions proceed smoothly to generate the corresponding biaryl compounds in moderate to excellent yields. Various biphenyl derivatives were successfully obtained by complex 4 catalysis of the Suzuki–Miyaura reactions in the absence of any surfactants in neat water. Copyright © 2013 John Wiley & Sons, Ltd.